Vinyl acetate vapors are uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in plugging of vents. This monomer is used principally in the production of polyvinyl acetate pvac and other vinyl acetate copolymers. All books are in clear copy here, and all files are secure so dont worry about it. Material safety data sheet ethylene vinyl acetate copolymer 14% vinyl acetate. Dusts and vapours or fumes evolved during thermal processing may cause irritation to the respiratory.
Vinyl acetate is a colorless, flammable liquid that also has a characteristic smell that can quickly become irritating. Vinyl acetate emulsion polymerization and copolymerization with acrylic monomers provides a collection and logical organization of the published data much of it formerly found fragmented. Download technical data sheet vinyl acetate monomer vam download sds. Disclaimer of expressed and implied warranties the information presented in the material safety data sheet is based on data believed to be accurate as of.
Ethylene vinyl acetate copolymer does not have an acid odor if it is not thermally degraded. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. D559418a standard test method for determination of the vinyl acetate content of ethylene vinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir vinyl acetate content ethylene vinyl acetate copolymer. The invention relates to vinyl acetateethylene copolymer emulsion vae emulsion and a synthesis method thereof. Presented at the 2006 ieee 4th world conference on photovoltaic energy conversion. Acute shortterm inhalation exposure of workers to vinyl acetate has resulted in eye irritation and upper. Polyvinyl acetate sds ghs, msds sheet of manufacturers. If there is potential for inhalation of dust or vapor, wear a niosh approved respirator. Signs and symptoms of acute vinyl acetate monomer exposure. Polyvinyl acetate is a precursor of polyvinilyc alcohol and polyvinyl acetate resins pva. Material safety data sheet or sds for vinyl acetate 803184 from merck for download or viewing in the browser. It is very flammable and may be ignited by heat, sparks, or. Vinyl acetate emulsion polymerization and copolymerization.
Information concerning particular hazards for human and environment. George wypych, in handbook of odors in plastic materials second edition, 2017. Vinyl acetate monomer is chemical building block used for a wide variety of. This monomer is used principally in the production of polyvinyl acetate pvac and other. This msds has been prepared according to the hazard criteria of t he controlled products regulations cpr and the msds contains all of the information required by the cpr. Weight percent vinyl acetate varies from 10 to 40 %. Acute shortterm inhalation exposure of workers to vinyl. Aug 25, 2017 vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. Material safety data sheet according to 19072006ec, article 31. Revised october 24, 2006 flexible vinyl msds material. Msds vam vinyl acetate monomer acetic acid explosive material. The physical and chemical properties of vinyl acetate are shown in table 32. Material safety data sheet msds vinyl acetate monomer s.
Vinyl acetate monomer presenation free download as powerpoint presentation. Vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. The basis for the proposed limits is an epidemiologic report by deese and joyner 1969ex. Download vinyl acetate monomer safety data sheet international. D559418a standard test method for determination of the vinyl acetate content of ethylenevinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir vinyl acetate content.
The synthesis method comprises the processes of preemulsification, emulsion polymerization reaction, finishing and defoaming. Vaporphase vinyl acetate may also be deg raded in the atmosphere by reaction with ozone with an estimated halflife of 3. Vinyl acetate 108054 trace trace impurities and additional material. A wide variety of msds vinyl acetate options are available to you, such as grade. Cn102030858b vinyl acetateethylene copolymer emulsion. Copying andor downloading of this information for the purpose of properly utilizing 3m. Before using or handling vinyl acetate monomer vam, read the material safety data sheet msds, safety data sheet sds and any other materials provided by your supplier. Material safety data sheet according to 19072006ec.
Vinyl acetate monomer vinyl ester acetic acid back to top product overview vinyl acetate monomer vam is an essential chemical building block used in a wide variety of industrial and consumer. Identification of the substancemixture and of the responsible company 1. View or download the vinyl acetate msds material safety data sheet or sds for 803184 from merck. Vinyl acetate is used to make other industrial chemicals. The invention relates to vinyl acetate ethylene copolymer emulsion vae emulsion and a synthesis method thereof. Ethylene vinyl acetate evapolyvinyl chloride graft copolymer taiyo vinyl tg. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate. Msds, safety data sheet sds and any other materials provided. Vinyl acetate 108054 hazard summary vinyl acetate is primarily used as a monomer in the production of polyvinyl acetate and polyvinyl alcohol. Revised october 24, 2006 flexible vinyl msds material safety. Msds of ethylene vinyl acetate emulsion ethylene vinyl acetate emulsion da128h download file pdf.
Sep 28, 2011 vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. Guide is intended to be used in conjunction with the manufacturers information. Sigmaaldrich offers a number of vinyl acetate products. Vinyl acetate is an industrial chemical that is produced in large amounts in the united states. Material safety data sheet ehylenevinyl acetate copolymer section 1 product and company identification. Msds vam vinyl acetate monomer free download as pdf file. Material safety data sheet of vinyl acetate monomer. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. Material safety data sheet polyvinyl acetate, average m. The synthesis method comprises the processes of preemulsification, emulsion. Before using or handling vinyl acetate monomer vam, read the material safety data sheet. Vinyl acetate from ethylene, acetic acid and oxygen. Biodegradability of polyvinyl acetate and related polymers article pdf available in advances in polymer science 245.
It is a clear, colorless liquid with a sweet, fruity smell. These polymers are the base for many industrial and consumer products as well as for other polymers. Material safety data sheet poly vinyl acetate, average m. This product has been classified in accordance with the hazard. Astm d5594 18a standard test method for determination of. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. When handled properly, vam can be stored, transported and otherwise managed safely. Vinyl acetate monomer may irritate the skin, eyes, and respiratory tract. These polymers are the base for many industrial and.
Potential problems with ethylenevinyl acetate for photovoltaic packaging poster author. Please ensure that this msds is given to, and explained to people using this product. Vinyl acetate monomer vam silver fern chemical inc. Dusts and vapours or fumes evolved during thermal processing may cause irritation to the respiratory system. International vinyl acetate company safety data sheet according to regulation ec no. Page 1 of 7 msds vinyl acetate monomer material safety data sheet msds vinyl acetate monomer 1. Vinyl acetate monomer polyvinyl chloride materials science. Polyvinyl acetate sds ghs, msds sheet of manufacturers commercial pure, bp and fcc food grade polyvinyl acetate sds ghs, msds sheet of manufacturers anmol chemicals is the pioneer. Vinyl acetate monomer vam is a high volume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Cn102030858b vinyl acetateethylene copolymer emulsion vae. Material safety data sheet ehylene vinyl acetate copolymer section disposal considerations waste disposal the generation of waste should be avoided or minimized wherever possible. Vinyl acetate monomer free download as powerpoint presentation. Vinyl acetate monomer vam is used for the production of polymer emulsions of various types, which are base resins for waterbased paints, adhesives, paper coatings and textile finishes.
Vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. Ethylene vinyl acetate eva is a random copolymer of ethylene and varying amounts of vinyl acetate va. Material safety data sheet according to 19072006ec, article 31 2. Otherinformation hazardousmaterialinformationsystemusa health 1 firehazard 0 reactivity 0 disclaimer the. With free acrobat readerr software you can view and print adobe pdf files.
Pdf biodegradability of polyvinyl acetate and related. Material safety data sheet of vinyl acetate monomer slideshare. Product and company information hoehn plastics inc. A wide variety of msds vinyl acetate options are available to you, such as grade standard. Vinyl acetate monomer safety data sheet international vinyl acetate company safety data sheet according to regulation ec no. Vinyl acetate monomer presenation personal protective. Vinyl acetate monomer safety data sheet international. Acute exposure to vinyl acetate monomer may require decontamination and life support for the victims. Find msds or sds, a coa, data sheets and more information. Material safety data sheetmsds ethyl acetate synonyms. Potential problems with ethylene vinyl acetate for photovoltaic packaging poster author. This product is not dangerous under directive 199945ec and subsequent amendments. Vinyl acetate occurs as residual monomer in homo and copolymers based on vinyl acetate and in products or formulations based on these polymers. The chemical identity of vinyl acetate is shown in table 31.
Vam can be polymerized in mass, solution, suspension or emulsion. Vinyl acetate is the acetate ester of vinyl alcohol. Eu risk assessment vinyl acetate summary, 2008 8 copolymers. Vinyl acetate is a particularly interesting substrate, since, as mentioned earlier, it gives 2acetoxypropanal, a precursor in the strecker synthesis of threonine. It is very flammable and may be ignited by heat, sparks, or flames.
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